Madara Uchiha along with reincarnated characters like Asuma and the Fourth Kazekage are playable characters in Naruto Shippuden: Ultimate Ninja Storm 3. That Madara boss fight looks intense with five Kages teaming up to fight Madara encased in Susanoo. I like how players can choose fights from a map too that should add more variation to story mode.
Naruto Shippuden: Ultimate Ninja Storm 3 comes out today in North America and later this week in Europe. Japan has to wait until April to play the game.